kianpetroleum

What is paraffin?

پارافین

Table of contents

تاریخ بروزرسانی(Update Date): 9th April 2025

What is Paraffin?

Paraffin generally refers to two main concepts. In the first concept, paraffin refers to a group of saturated hydrocarbon molecules known as alkanes. Alkanes are simple compounds made of carbon and hydrogen with only single bonds, which give them high chemical stability due to their saturated structure. Everything from light gases like propane and butane to compounds with over 40 carbons is considered an alkane or paraffin.

In the second concept, paraffin refers to a hydrocarbon material that is primarily obtained from crude oil refining, although it can also be extracted from sources like coal and oil shale. Depending on the production process, paraffin is available in both liquid and solid forms, and due to its unique properties, it is used in various applications such as candle-making, cosmetic and healthcare products, heating fuels, and lubricants. This substance is insoluble in water but can dissolve in solvents such as ether, benzene, and certain esters. Due to its high chemical stability, paraffin is resistant to many common reagents and is regarded as an essential derivative of crude oil with a significant role in various industries.

History of Paraffin Discovery

Paraffin was first discovered and produced in the 1830s by German scientist Karl Reichenbach. He managed to obtain a solid, transparent material from derivatives of oil and coal through a refining process, which later replaced traditional candles and revolutionized the candle-making industry. Prior to paraffin, candles were made from tallow, which had numerous drawbacks when burned. However, paraffin burned uniformly and without smoke and was cheaper to produce than traditional candles, thus easily replacing them.

Initially, paraffin faced challenges such as a low melting point, which made it more sensitive to heat. But over time, refining processes improved, and new materials like stearic acid were added to paraffin to increase its melting point and enhance its stability. These improvements helped paraffin become an ideal material widely used in various industries, particularly in candle-making, cosmetic and healthcare products, and even pharmaceuticals, earning it a special place in these fields.

Types of Paraffin

Liquid Paraffin

Liquid paraffin is a colorless, transparent, and odorless substance that remains liquid at room temperature. With relatively high viscosity and chemical stability, it is used across various industries, primarily in cosmetics and personal care products as a softener and moisturizer. Due to its lubricating properties, it is also used in producing industrial lubricants and machinery parts. Additionally, liquid paraffin is utilized in the production of certain drugs and fuels and is recognized as a safe and non-irritating substance.

Solid Paraffin

Solid paraffin is a white or colorless, odorless, and tasteless substance with high chemical stability due to its saturated hydrocarbon structure. It is physically divided into crystalline and regular types. Crystalline paraffin has a more organized and transparent structure, commonly used in applications that require a transparent and special appearance, such as transparent candles and some cosmetic products. The other type, non-crystalline paraffin, is used in more general applications like regular candle-making, insulation, and packaging industries.

Difference Between Solid and Liquid Paraffin

Solid and liquid paraffin differ due to molecular structure and hydrocarbon chain length, impacting their boiling and melting points, as well as physical and chemical properties, ultimately resulting in paraffin appearing in various forms (liquid or solid).

Hydrocarbon Chain Length

Liquid paraffin has shorter hydrocarbon chains, whereas solid paraffin consists of longer hydrocarbon chains. Shorter chains allow the molecules to move more freely, resulting in a liquid state, while longer chains give paraffin a crystalline and solid property.

Boiling and Melting Points

Liquid and solid paraffin melt and boil at different temperatures due to the differences in chain length and molecular weight. Liquid paraffin has lower boiling and melting points, which is why it remains liquid at room temperature. In contrast, solid paraffin, with a higher melting point, stays solid at room temperature.

Production and Refining Process

Different processes are used in the production of liquid and solid paraffin, affecting the final product’s properties. Liquid paraffin is obtained from lighter components of crude oil and distilled at lower temperatures, with special refining processes to maintain a liquid state. Solid paraffin, however, is made from heavier components through specialized crystallization processes.

Molecular Structure and Stability

Solid paraffin has a crystalline molecular structure, while liquid paraffin has freer, non-crystalline molecules. This crystalline structure helps solid paraffin stay stable against temperature changes, maintaining its solid form at room temperature. Because of this structure, solid paraffin is less affected by environmental pressure or temperature changes and has greater stability. In contrast, liquid paraffin easily responds to environmental temperature and pressure, making it suitable for use in oils and cosmetic and personal care products.

Physical and Practical Characteristics

Each type of paraffin has unique characteristics that make it suitable for various applications. Solid paraffin’s firm and stable structure makes it ideal for manufacturing candles, packaging materials, paraffin papers, and even in the rubber and plastics industries. On the other hand, liquid paraffin, with its lubricating ability and high transparency, is widely used in cosmetics, personal care, and pharmaceutical products such as creams and lotions. Liquid paraffin is also a suitable base for producing pharmaceutical products and skin softeners.

Chemical Properties

Both solid and liquid paraffin are saturated hydrocarbons, with high resistance to oxidation and decomposition due to their single carbon-carbon bonds. However, because of different structures and chain lengths, their chemical properties differ slightly. Liquid paraffin, due to its shorter chains, is slightly more reactive and can undergo changes in the presence of certain chemicals and at high temperatures. Solid paraffin, with its crystalline structure, demonstrates greater stability against various environmental conditions.

Production of Paraffin from Crude Oil

Liquid Paraffin

Liquid paraffin, also known as “mineral oil,” is extracted from petroleum compounds and is widely used in the pharmaceutical, cosmetic, and even food industries due to its high purity and non-toxic properties. The production process for liquid paraffin includes steps such as distillation, primary purification, hydrogen refining, final purification, and packaging.

The production of liquid paraffin begins with the distillation of crude oil. In this stage, crude oil is heated in distillation columns, and its various components are separated based on boiling points. Lighter petroleum substances with shorter chains are separated at lower temperatures, and some of them are used to produce liquid paraffin.

After distillation, the separated materials undergo an initial purification process to remove impurities such as sulfur, nitrogen, and aromatic compounds. This stage ensures that liquid paraffin is obtained with higher purity, ready for subsequent refining stages.

In this stage, the petroleum substance undergoes hydrogenation, which helps reduce sulfur levels and other harmful compounds. By adding hydrogen to the composition, the structure of paraffin becomes more stable and purified, resulting in a higher-quality product. This stage is critical, as it makes liquid paraffin more suitable for use in personal care and pharmaceutical products.

Following hydrogenation, liquid paraffin undergoes a final purification process. At this stage, precise filters and specific methods are used to remove any remaining impurities. This final purification ensures the high transparency and purity of the liquid paraffin.

Finally, the liquid paraffin is packaged in bottles or specialized containers to maintain its quality. Proper and hygienic packaging is essential to prevent contamination and preserve the properties of liquid paraffin, and the product is ready for the market.

Solid Paraffin

Solid paraffin is also produced through a multi-step process, including distillation, primary purification, solidification, final purification, and packaging. Each of these steps plays a crucial role in the purity and quality of the final solid paraffin product.

In the first stage, crude oil is distilled. Crude oil is heated in distillation columns to separate its components based on boiling points. In this process, parts of the oil containing paraffinic substances with longer hydrocarbon chains are separated, forming the primary basis for producing solid paraffin.

In the next step, primary purification is performed to remove impurities present in the extracted paraffinic materials. This stage uses filters and specific chemicals to eliminate impurities, sulfur, and other unwanted materials. This step is essential for ensuring the quality and purity of paraffin and helps improve its properties.

Then, the solidification or crystallization process begins. At this stage, the paraffinic material is cooled to a lower temperature to solidify. Paraffin crystals form at this stage, making the paraffin solid and ready for further processing steps. These crystals form the solid foundation of the final product.

Next, a final purification is carried out. At this stage, centrifuges or highly precise filters are used to separate any remaining oil or impurities in the solid paraffin. This final purification increases the purity and quality of solid paraffin, making it suitable for use in various products.

In the last stage, paraffin is transferred to packaging. Solid paraffin is shaped into blocks, sheets, or various molds and then packaged. Proper and careful packaging is crucial for maintaining quality and preventing contamination of the final product, and the solid paraffin is ready for distribution to the market.

Applications of Paraffin

Liquid Paraffin

پارافین مایع

Cosmetic and Personal Care Products (Creams, Lotions, Lip Balms)

Liquid paraffin is effectively used in cosmetic and personal care products such as creams, lotions, and lip balms as a moisturizer and softener. By creating a protective layer on the skin’s surface, it prevents moisture loss and helps retain skin hydration. Therefore, products containing liquid paraffin are highly beneficial for treating and preventing dry and cracked skin. Additionally, with its non-irritating and odorless structure, liquid paraffin is a suitable choice for sensitive skin. Lip balms containing paraffin also prevent chapping and dryness, keeping lips soft and smooth.

Laxative in Specific Medications for Treating Constipation

Highly refined liquid paraffin, known as medicinal liquid paraffin, is used as an effective laxative for treating constipation. It forms an oily layer on the intestinal walls and stool, softening and lubricating the stool to facilitate its movement through the digestive tract. Medicinal liquid paraffin works without being absorbed by the body and solely acts as a lubricant to ease stool passage. This feature makes it especially suitable for individuals who need non-stimulant laxatives and avoids common issues associated with other laxatives, such as cramps and intestinal irritation.

Lubricant in Industrial Machinery

Liquid paraffin is widely used as a lubricant in industrial machinery. By forming a slippery layer between moving parts, it reduces friction and prevents wear and tear on components. Using liquid paraffin as a lubricant extends the lifespan of parts and reduces the need for frequent repairs. Additionally, due to its thermal stability, liquid paraffin performs well at high temperatures, maintaining its efficiency even under the high-temperature and high-pressure conditions found in industrial settings.

Fuel

Liquid paraffin is used as a fuel in heating and lighting devices, such as oil heaters, oil lamps, and camping lanterns. This fuel has a high flash point, offering a suitable level of safety and posing less risk of explosion and fire compared to many other liquid fuels. Moreover, liquid paraffin produces neither soot nor unpleasant odor when burned, making it suitable for enclosed spaces and areas with limited ventilation. However, despite its favorable characteristics, liquid paraffin is not ideal for camping, where isobutane gas or a propane-isobutane mixture is recommended.

Solid Paraffin

پارافین جامد

Candle Making

Solid paraffin is one of the primary materials used in the candle-making industry. Due to its suitable melting point, moldability, and even, controlled burn, it is ideal for producing various types of candles, including household, decorative, and ceremonial candles. Solid paraffin melts easily and, due to its high chemical stability, produces minimal soot while burning and provides a stable and clear flame, offering optimal illumination. Additionally, candles made from solid paraffin can burn for long periods, making them ideal for use in various settings and occasions.

Rubber and Plastic Manufacturing

Solid paraffin is used as an effective additive in the rubber and plastic industries. It provides anti-stick properties to product surfaces, preventing rubber and plastic from adhering to molds and facilitating the production process. Moreover, solid paraffin acts as a stabilizer in these industries, helping to maintain quality and increase the resistance of products against environmental factors like heat and sunlight. Using solid paraffin in rubber and plastic production enhances the durability and longevity of final products, preventing premature cracking and wear.

Thermal and Electrical Insulation

Solid paraffin is used as an insulator in thermal and electrical industries. Its moisture-resistant and heat-resistant properties make it ideal for insulating electrical and thermal equipment. In electrical insulation, solid paraffin serves as a protective coating for wires and sensitive components, preventing leakage currents and reducing the risks associated with short circuits. In thermal insulation, paraffin is used as a thermal energy storage material, absorbing and gradually releasing heat to maintain a stable temperature range. These features make solid paraffin a suitable choice for ensuring safety and efficiency in thermal and electrical equipment.

Cosmetic and Personal Care Products

Solid paraffin is used as a stabilizing and protective agent in the production of cosmetic and personal care products, such as lipstick, skin creams, and softening products. It creates a smooth and even texture, allowing the final product to spread well on the skin and lips with increased longevity. Additionally, due to its protective properties, solid paraffin prevents contamination and moisture loss, keeping the skin and lips soft and supple.

Differences in the Use of Liquid and Solid Paraffin in Cosmetic and Personal Care Products

In the production of cosmetic and personal care products, liquid and solid paraffin have distinct applications. Liquid paraffin is mainly used as a moisturizer and softener, creating a protective layer on the skin to prevent moisture loss. This feature makes it suitable for creams, lotions, and lip balms. In contrast, solid paraffin is used as a stabilizing and structuring agent that gives texture and firmness to the product, making it ideal for products requiring greater protective qualities, such as lipstick and skin-protective products.

Industrial, Chlorinated, and Granular Paraffin

Industrial Paraffin

Industrial paraffin is a type of paraffin with lower purity, designed for industrial and non-cosmetic uses, and can be in liquid or solid form. Due to its higher impurity levels compared to cosmetic-grade paraffin, it is not suitable for direct application on the skin, but it has extensive applications in various industries. In solid form, industrial paraffin is used as an anti-stick agent in molds, for insulation, and as a lubricant. In liquid form, it serves as a lubricant for machinery, an additive in adhesives, and even as a material in rubber and plastic production.

Chlorinated Paraffin

Chlorinated paraffin is a type of paraffin produced through chlorination and can be in solid or liquid form, depending on the amount of chlorine present. Chlorinated paraffin has fire-resistant properties, high chemical resistance, and lubricating characteristics, making it suitable for use in various industries. This type of paraffin is commonly used in the production of rubber, plastic products, paints, and metal lubricants, and as an additive to improve the heat and chemical resistance of materials. Chlorinated paraffin with a low chlorine percentage is usually in liquid form, while those with a high chlorine content are solid.

Granular Paraffin

Granular paraffin is a type of solid paraffin produced in the form of small granules. This granular form facilitates easier handling and usage, making it simple to measure and add to various mixtures. Granular paraffin is primarily used in industries such as candle-making, rubber manufacturing, and the production of cosmetic and personal care products. Due to its stability and suitable melting point, granular paraffin is an ideal choice for applications requiring precise control over the amount and composition of materials.

Are Paraffin and Vaseline the Same?

Although paraffin and vaseline are both petroleum products and share some similarities, they are not the same. Paraffin is available in liquid, solid, or semi-solid forms and is primarily used as a softener and lubricant in the cosmetic, healthcare, and chemical industries. Liquid paraffin is used as a moisturizing agent in skin products, but in general, paraffin compounds consist of saturated hydrocarbons used in the formulation of various materials.

Vaseline, or petroleum jelly, is a product made from heavier petroleum substances and has a semi-solid gel form. Due to its moisturizing and protective properties, vaseline is widely used in skin products and for treating wounds and dry skin. This substance creates a protective barrier on the skin, preventing moisture loss.

Paraffin and the Environment

The production of paraffin leads to the release of greenhouse gases such as carbon dioxide and methane, contributing to global warming and climate change. Additionally, during the refining and production process, chemical waste and pollutants are generated, which, if not properly managed, can seep into water and soil, harming ecosystem health.

The improper use and disposal of industrial paraffin and paraffin-containing products can also threaten the environment. Paraffin is non-biodegradable and can remain in the environment for a long time. When paraffin or its residues are released into nature, they can harm water sources, soil, and living organisms. Therefore, it is essential that the production, use, and disposal of paraffin are controlled under appropriate environmental regulations to minimize its harmful impact on nature.